# If you change the alias database, run "postalias /etc/aliases" (or
# wherever your system stores the mail alias file), or simply run
# "newaliases" to build the necessary DBM or DB file.
#
# It will take a minute or so before changes become visible. Use
# "postfix reload" to eliminate the delay.

ってmain.cfに書いてあるけどpostfix reloadはしたの？